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Princeton HPLC Columns
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Princeton Chiral Columns
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The chiral phases, DNB-LEU or DNB-PHGLY, are prepared from N-3-5-dinitrobenzoyl
protected derivatives of leucine or phenylgylcine, (which are then bonded to
silica stationary phase). These phases are available in both the D- or the L-
enantiomers of the amino acids.
The unique feature of amino-acid-derived chiral phases is that the
elution order of enantiomers in the sample is dependent on the D- or L- chirality
of the bonded amino acid. Therefore, the order of elution can be controlled
by appropriate selection of stationary phase. This can be of tremendous
advantage for those samples which contain a large excess of one
enantiomer, in which case it is desirable to have the minor component elute first.
Many racemic acids and amines which cannot be resolved in their native
form can be easily converted to amides or anilides which can be
resolved by an amino-acid-derived chiral phase. The following compounds
are candidates for amino-acid-derived chiral phases:
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Aromatic alcohols
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Aryl substituted phthalides
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Aromatic amino acids
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Aryl substituted lactams
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Aromatic amino alcohols
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Aryl substituted succinamides
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Aromatic thiols
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Aryl substituted hydantoins
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Aromatic amines
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Aryl substituted hydantoins
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Aromatic sulfoxides
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Aryl substituted hydantoins
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Mandelic acid analogs
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Aryl substituted hydantoins
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Phase: D-DNB-LEU
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Part #
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Length x ID
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Particle Size
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Price
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Buy
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250046-03511
|
250 x 4.6 mm
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5 µm
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$700.00
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150046-03511
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150 x 4.6 mm
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5 µm
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$675.00
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150046-03311
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150 x 4.6 mm
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3 µm |
$750.00
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100046-03311
|
100 x 4.6 mm
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3 µm
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$700.00
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250040-03511
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250 x 4.0 mm
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5 µm
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$700.00
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150040-03511
|
150 x 4.0 mm
|
5 µm
|
$675.00
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150040-03311
|
150 x 4.0 mm
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3 µm
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$750.00
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100040-03311
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100 x 4.0 mm
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3 µm |
$700.00
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250030-03511
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250 x 3.0 mm
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5 µm |
$700.00
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150030-03511
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150 x 3.0 mm
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5 µm
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$675.00
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150030-03311
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150 x 3.0 mm
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3 µm
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$750.00
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100030-03311
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100 x 3.0 mm
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3 µm |
$700.00
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250020-03511
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250 x 2.0 mm
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5 µm |
$750.00
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150020-03511
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150 x 2.0 mm
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5 µm
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$700.00
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150020-03311
|
150 x 2.0 mm
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3 µm
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$775.00
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100020-03311
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100 x 2.0 mm
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3 µm
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$725.00
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Phase: L-DNB-LEU
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Part #
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Length x ID
|
Particle Size
|
Price
|
Buy
|
|
250046-03512
|
250 x 4.6 mm
|
5 µm
|
$700.00
|
|
|
150046-03512
|
150 x 4.6 mm
|
5 µm
|
$675.00
|
|
|
150046-03312
|
150 x 4.6 mm
|
3 µm
|
$750.00
|
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|
100046-03312
|
100 x 4.6 mm
|
3 µm
|
$700.00
|
|
|
250040-03512
|
250 x 4.0 mm
|
5 µm
|
$700.00
|
|
|
150040-03512
|
150 x 4.0 mm
|
5 µm
|
$675.00
|
|
|
150040-03312
|
150 x 4.0 mm
|
3 µm
|
$750.00
|
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|
100040-03312
|
100 x 4.0 mm
|
3 µm
|
$700.00
|
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|
250030-03512
|
250 x 3.0 mm
|
5 µm
|
$700.00
|
|
|
150030-03512
|
150 x 3.0 mm
|
5 µm
|
$675.00
|
|
|
150030-03312
|
150 x 3.0 mm
|
3 µm
|
$750.00
|
|
|
100030-03312
|
100 x 3.0 mm
|
3 µm
|
$700.00
|
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250020-03512
|
250 x 2.0 mm
|
5 µm
|
$750.00
|
|
|
150020-03512
|
150 x 2.0 mm
|
5 µm
|
$700.00
|
|
|
150020-03312
|
150 x 2.0 mm
|
3 µm
|
$775.00
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1000206-03312
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100 x 2.0 mm
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3 µm
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$725.00
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Phase: D-DNB-PHGLY
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Part #
|
Length x ID
|
Particle Size
|
Price
|
Buy
|
|
250046-03513
|
250 x 4.6 mm
|
5 µm
|
$700.00
|
|
|
150046-03513
|
150 x 4.6 mm
|
5 µm |
$675.00
|
|
|
150046-03313
|
150 x 4.6 mm
|
3 µm
|
$750.00
|
|
|
100046-03313
|
100 x 4.6 mm
|
3 µm
|
$700.00 |
|
|
250040-03513
|
250 x 4.0 mm
|
5 µm
|
$700.00
|
|
|
150040-03513
|
150 x 4.0 mm
|
5 µm
|
$675.00
|
|
|
150040-03313
|
150 x 4.0 mm
|
3 µm |
$750.00
|
|
|
100040-03313
|
100 x 4.0 mm
|
3 µm
|
$700.00 |
|
|
250030-03513
|
250 x 3.0 mm
|
5 µm
|
$700.00
|
|
|
150030-03513
|
150 x 3.0 mm
|
5 µm
|
$675.00
|
|
|
150030-03313
|
150 x 3.0 mm
|
3 µm
|
$750.00
|
|
|
100030-03313
|
100 x 3.0 mm
|
3 µm
|
$700.00 |
|
|
250020-03513
|
250 x 2.0 mm
|
5 µm
|
$750.00
|
|
|
150020-03513
|
150 x 2.0 mm
|
5 µm
|
$700.00
|
|
|
150020-03313
|
150 x 2.0 mm
|
3 µm
|
$775.00
|
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100020-03313
|
100 x 2.0 mm
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3 µm
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$725.00 |
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Phase: L-DNB-PHGLY
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Part #
|
Length x ID
|
Particle Size
|
Price
|
Buy
|
|
250046-03514
|
250 x 4.6 mm
|
5 µm
|
$700.00
|
|
|
150046-03514
|
150 x 4.6 mm
|
5 µm
|
$675.00
|
|
|
150046-03314
|
150 x 4.6 mm
|
3 µm
|
$750.00
|
|
|
100046-03314
|
100 x 4.6 mm
|
3 µm
|
$700.00
|
|
|
250040-03514
|
250 x 4.0 mm
|
5 µm
|
$700.00
|
|
|
150040-03514
|
150 x 4.0 mm
|
5 µm
|
$675.00
|
|
|
150040-03314
|
150 x 4.0 mm
|
3 µm
|
$750.00
|
|
|
100040-03314
|
100 x 4.0 mm
|
3 µm
|
$700.00
|
|
|
250030-03514
|
250 x 3.0 mm
|
5 µm
|
$700.00
|
|
|
150030-03514
|
150 x 3.0 mm
|
5 µm
|
$675.00
|
|
|
150030-03314
|
150 x 3.0 mm
|
3 µm
|
$750.00
|
|
|
100030-03314
|
100 x 3.0 mm
|
3 µm
|
$700.00
|
|
|
250020-03514
|
250 x 2.0 mm
|
5 µm
|
$750.00
|
|
|
150020-03514
|
150 x 2.0 mm
|
5 µm
|
$700.00
|
|
|
150020-03314
|
150 x 2.0 mm
|
3 µm
|
$775.00
|
|
|
100020-03314
|
100 x 2.0 mm
|
3 µm
|
$725.00
|
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